氧分压对Ni-Cr-Fe合金氧化成膜特性影响的研究     

李厚敏  初蕾  刘英才  梁丹维 《中国海洋大学学报(自然科学版)》2011,(Z1):267-271

以铸态Ni-Cr-Fe合金为试样,于1 050℃湿氢气氛下恒温氧化20 h。通过氧化增重、SEM/EDS以及薄膜X-射线衍射等方法研究了氧分压对该合金在弱氧化性气氛下氧化成膜特性的影响。结果表明:表面氧化膜从外到内氧化物组成依次为:MnCr2O4、Cr2O3以及SiO2。氧化膜的厚度、组成及形貌与体系的氧分压密切相关,中等氧分压(15.9×10-18atm)有利于表面尖晶石的形成;较低氧分压有利于形成厚而多孔的氧化膜,而高氧分压则趋向于形成薄而致密的氧化膜。  相似文献   

莺歌海盆地莺歌海组二段泥岩盖层封闭性综合评价   总被引：2，自引：0，他引：2  

冯冲  黄志龙  童传新  朱建成  范泓澈  刘江涛 《地球科学与环境学报》2011,33(4):373-377

通过实测莺歌海盆地莺歌海组二段泥岩盖层的排替压力,建立了盖层排替压力与声波时差的线性关系,进而提出了利用声波时差及地震速度资料求取排替压力的方法.接着,利用测井声波时差和地震速度资料,按等效深度法确定莺歌海组二段下部泥岩盖层的超压分布.综合考虑盖层累计厚度、排替压力、剩余压力、气藏内部压力、断裂对盖层破坏程度和天然气本...  相似文献   

Reproductive biology of Spondias tuberosa Arruda (Anacardiaceae), an endemic fructiferous species of the caatinga (dry forest), under different management conditions in northeastern Brazil     

A.L.S. Almeida  C.C. Castro 《Journal of Arid Environments》2011,75(4):330-337

In areas under different management conditions (management units, MUs) located either on a slope or at the base of a slope and either in a plantation or in a pasture, we compared the flower and fruit production, floral visitors, visitation rates and pre-emergent reproductive success (PERS) of Spondias tuberosa (Anacardiaceae) in an area of dry forest in NE Brazil. Individuals in the plantation MU produced more flowers per inflorescence than those in other MUs, but there were no statistical differences in mean fruit set among MUs. The only difference in mean visitation rates was between the plantation (65.83 ± 38.49) and the slope sites (11.5 ± 12.8). We observed visits by 19 insect species, including bees (31.6%), butterflies (31.6%), wasps (26.3%) and flies (10.5%). A clustering analysis based on the number of visits showed that a) the plantation site is most different from the other MUs, b) the pasture and the site at the base of the slope are similar to the slope site, and c) the higher frequency of visits of pollinators in the plantation MU was responsible for these differences. Of the 19 species of insects visiting the flowers, 12 were considered pollinators. The pollinator similarity analysis indicated a clear separation between areas and suggested that human activity has resulted in the replacement of native pollinators by exotic species. However, these changes apparently have not affected the pre-emergent reproductive success of S. tuberosa. Our results show that plant reproductive biology in semi-arid ecosystems may be modified by human action and that changes in floral production and pollinator guilds are the most conspicuous effects. However, the traditional management performed by local people may not affect the reproductive success of plant species.  相似文献   

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS          下载免费PDF全文

Zaicong Wang  Harry Becker  Frank Wombacher 《Geostandards and Geoanalytical Research》2015,39(2):185-208

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.  相似文献   

浅谈高温高压实验地球科学:方法和应用     

杨晓志 《矿物岩石地球化学通报》2015,(3)

在过去的二十多年间,高温高压实验地球科学研究得到了蓬勃发展,凭借其高度的灵活性和易于与其他分支学科相结合的优点,在很多不同的研究领域中都取得了令人瞩目的成果,并已发展成为国际地球科学的前沿领域和重要方向之一,同时也是固体地球科学最强有力研究手段之一。相比之下,国内的高温高压实验地球科学研究还显得相对比较薄弱,相关系统性的认识还有待增强。本文对高温高压实验研究的发展历程、方法原理、仪器设备以及在地球科学研究中的一些应用进行简单的介绍,旨在让更多的国内学者对这一领域有更深入的了解。  相似文献   

二氧化碳洗井中相关问题的探讨     

樊小舟  高波  崔秀忠 《中国煤炭地质》2015,(1):62-65

二氧化碳洗井方法具有设备简单、用时少,效果好的特点,但随着钻孔深度和孔径加大,井管材料的更新换代,有时也会难以出现壮观的井喷场面,达不到理想的洗井效果,使用范围受到限制的问题。总结多年的洗井经验,依据二氧化碳洗井原理,运用洗井过程中起动压力和用气量的计算公式,进而对洗井深度和影响用气量的因素进行了分析,结果表明:1该方法比较适用于井深300m左右、孔径Φ325mm以内、泥浆相对密度小于1.1g/cm3的新打水井,对大于300m的深井,可采用分层洗井法或压风机引喷法进行洗井。2井喷形成时的二氧化碳气体用量,与瓶内气体的压力、钻杆的下入深度、环空体积、地面管路的长度与直径、钻杆内径、钻井液的密度等成正比,而与水温、气温等成反比;当井的含水层的水柱高度低于70m时,一般不易形成井喷。3二氧化碳洗井适用于井内下入钢管、铸铁管等抗压强度较高的井。对水泥管、塑料管等强度较低的井管则要视情况具体分析。  相似文献   

川中地区上三叠统须家河组气田异常高压演化研究   总被引：1，自引：0，他引：1  

马德文  邱楠生  谢增业  许威 《沉积学报》2011,29(5):953-961

根据川中地区上三叠统须家河组典型气田的现今实测地层压力分析了异常高压发育的特征。以现今实测压力为约束,利用流体压实耦合方法恢复了须家河组气田主要储层的压力演化史。研究结果表明：上三叠统须家河组储层超压的发育在总体上是逐渐增大的,其地层压力演化可划分为三个阶段：（1）150 Ma之前为常压阶段,地层压力等于静水压力;（2...  相似文献   

西藏尼木变质岩特征及变质温压条件     

孙凯  周肃  赵志丹  张琳琳  刘栋 《岩石学报》2011,27(12):3718-3726

出露于雅鲁藏布江缝合带北侧尼木县的变质岩主要由石榴黑云片麻岩和黑云斜长角闪角岩组成.研究表明岩石变质程度达到角闪角岩相-辉石角岩相;石榴子石变斑晶具有生长环带,角闪石均为钙质角闪石,黑云母大多为铁质黑云母和铁叶云母,长石多为更长石和中长石,少量为正长石.利用石榴子石-黑云母温度计、石榴子石-黑云母-斜长石-石英压力计和角闪石-斜长石温度及压力计计算获得石榴黑云片麻岩和黑云斜长角闪角岩的变质温度分别为619 ～661℃,695 ～ 702℃,压力范围分别为1.86～1.94kbar和3.69～4.56kbar.野外和室内研究认为岩石原岩为冈底斯带南缘叶巴组火山岩及其上部沉积岩,岩石经历了高温低压的接触变质作用.结合已有冈底斯带陆缘岩浆活动特征,对变质岩的形成环境和过程进行了反演.  相似文献   

地层温度对科学超深井井壁稳定的影响          下载免费PDF全文

张培丰 《探矿工程》2011,38(10):1-5

井壁稳定问题包括井壁坍塌和地层破裂2种基本类型,科学超深井钻探的目的层是处于高地应力、高地温和高地层压力的深部岩层,井壁稳定问题更加突出。以12000 m科学超深井为例,从地层温度入手,分析钻井液循环温度变化所引起的当量静态钻井液密度和环空压力当量密度的变化,以及温梯应力、温差应力对井壁稳定的影响。  相似文献   

提高钻孔桩桩底压浆工效及保证质量的技术措施          下载免费PDF全文

刘宝新  唐世杰  陈跃武 《探矿工程》2011,38(10):56-59

钻孔桩桩底压浆技术是向钻孔灌注桩桩底沉渣和围岩土体内压入一定量水泥浆,使桩底沉渣和桩底一定范围土体孔隙内充满水泥浆液,经物理、化学作用使其强度大幅提高,从而实现单桩竖向承载力的提高。结合高铁钻孔桩桩底压浆施工实践,介绍了2种压浆工艺过程,阐明了提高压浆工效、保证注浆质量关键技术措施实施的重要性。  相似文献